Arcidosso, which is famous for its chestnut festival, is surrounded by winding mountain roads bordered with forests and steep slopes that in the winter transform into some of central Italy's prime skiing spots. The northern side of Monte Amiata, which we reach after Arcidosso, with its picturesque scenery, is the perfect spot to snap a photo.
After 4km on the the SP160, you'll come to a small walled town: Montelaterone. The romantically inclined will want to walk along kissing alley, called as such because it's so narrow you could kiss a passer-by coming the other way. Castel del Piano is known for its folklore; it even has a Palio that sees neighborhoods go head to head in horse races every year on September 8.